REGIO- AND STEREO-SELECTIVITIES IN THE TITANIUM COMPLEX CATALYZED HYDROBORATION OF CARBON–CARBON DOUBLE BONDS IN VARIOUS UNSATURATED COMPOUNDS
- 5 May 1984
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 13 (5) , 673-676
- https://doi.org/10.1246/cl.1984.673
Abstract
The titanium complex prepared from TiCl3 and NaBH4 in THF in the presence of 18-crown-6 promotes the catalytic hydroboration of carbon–carbon double bonds in alkenes, alkadienes and unsaturated ethers with NaBH4, giving sodium organoborates which can be converted into alcohols by oxidation with H2O2/CH3ONa. The reaction proceeds with high regio- and stereo-selectivities.This publication has 6 references indexed in Scilit:
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