Estimation of bond dissociation energies, including DH°(RSCH2–H), from barriers to internal rotation
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 731-732
- https://doi.org/10.1039/c39840000731
Abstract
A Linear correlation between C–H bond dissociation energies in molecules of the type RCH2–H and the corresponding barriers to rotation about the ·CH2–R bonds is established and used to derive the Cα–H bond dissociation energy of sulphides.Keywords
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