Studies on cyclotene and its related compounds. Part VII. Synthesis of .OMEGA.-chain-modified analogues of 7-oxaprostaglandins.
- 1 January 1984
- journal article
- Published by Oxford University Press (OUP) in Agricultural and Biological Chemistry
- Vol. 48 (5) , 1123-1129
- https://doi.org/10.1271/bbb1961.48.1123
Abstract
ω-Methyl- 11 -deoxy-7-oxaprostaglandin (5a-t), co-methyl-9, 11-bisdeoxy-7-oxaprostaglandin (6a-t) and their related compounds having a gem-dimethyl, gem-methylethyl, gem-methylpropyl, gem-methylbenzyl or gem-methylallyl group as the ω-chain (5b-5f, 6b-6e) were synthesized starting from cyclotene (1), 2-hydroxy-3-methyl-2-cyclopenten-1 -one, which is a principal constituent of coffee aroma and maple flavor.Keywords
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