Calculation of Chemical Reaction Rates by the R-Matrix Method
- 1 September 1971
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 55 (5) , 2563-2570
- https://doi.org/10.1063/1.1676449
Abstract
The application of Wigner and Eisenbud's R‐matrix theory to chemical reactions is tested by calculation of reaction probabilities in collinear H+H2 collisions. Conclusions are drawn concerning resonances, statistical reactiontheories, and the calculation of reaction cross sections.Keywords
This publication has 41 references indexed in Scilit:
- Solvable Quantum-Mechanical Model of Three-Body Rearrangement ScatteringThe Journal of Chemical Physics, 1969
- Correlation of Experimental Rate Constants of the Hydrogen Exchange Reactions with a Theoretical H3 Potential Surface, Using Transition-State TheoryThe Journal of Chemical Physics, 1968
- Permeabilities and Transmission Coefficients for Various Isotopic Reactions of the Type H + H2=H2 + HThe Journal of Chemical Physics, 1968
- Quantum-Mechanical Treatment of Inelastic Collisions. II. Exchange ReactionsThe Journal of Chemical Physics, 1968
- Measurable consequences of a dip in the activation barrier for an adiabatic chemical reactionMolecular Physics, 1967
- The H + H2 reaction in two dimensionsDiscussions of the Faraday Society, 1967
- Quantum-mechanical study of H + H2 reactive scatteringDiscussions of the Faraday Society, 1967
- Semi-classical treatment of exchange processesTransactions of the Faraday Society, 1965
- Quantum-Mechanical Calculation of the Probability of an Exchange Reaction for Constrained Linear EncountersThe Journal of Chemical Physics, 1959
- The Transmission Coefficient in the Theory of Absolute Reaction RatesThe Journal of Chemical Physics, 1943