The vibrational spectra of ClF2SbF6, BrF2SbF6, and ClO2SbF6
- 1 November 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 48 (21) , 3456-3459
- https://doi.org/10.1139/v70-578
Abstract
Infrared and Raman spectra of ClF2SbF6, BrF2SbF6, and ClO2SbF6 are reported. Vibrational frequencies for the BrF2+ cation are assigned. In all compounds various degrees of anion–cation interaction are found. The symmetry of the anion is reduced but no internal similarity between the three spectra is recognizable. In addition, strong coupling of vibrational modes for BrF2SbF6 is observed.Keywords
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