The first mixed-valence MnII,III gallium phosphate: synthesis and structural characterization of (C4H12N2)2Mn2Ga5(H2O)(PO4)8
- 1 January 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 135-136
- https://doi.org/10.1039/a908334k
Abstract
The synthesis and characterization of a novel mixed-valence MnGaPO phase is described; the 3D open-framework consists of discrete bioctahedra of Ga2O10(H2O) and GaO5 trigonal bipyramids, connected via MnIIIO4, MnIIO4 and PO4 tetrahedra to generate intersecting tunnels within which piperazinium cations reside.Keywords
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