Mechanism of alkylidyne complex formation by protonation of the vinylidene complex trans-[ReCl(CCHPh)(Ph2PCH2CH2PPh2)2]
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1796-1797
- https://doi.org/10.1039/c39890001796
Abstract
Stopped-flow kinetic studies have demonstrated that in tetrahydrofuran the protonation of trans-[ReCl(CCHPh)(Ph2PCH2CH2PPh2)2] to form trans-[ReCl(CCH2Ph)(Ph2PCH2CH2PPh2)2]+ can occur by three pathways.Keywords
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