Preparation of (nonacarbonyltricobaltmethoxy)(tetracarbonylcobalt)-silicon(IV) derivatives
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2536-2537
- https://doi.org/10.1039/j19710002536
Abstract
Diphenyl- and diethyl-silane react with an excess of octacarbonyldicobalt to give compounds of the formula R2SiCo4(CO)14(R = Et, Ph). High resolution i.r. and mass spectra strongly suggest that these derivatives contain nonacarbonyltricobaltmethoxy- and tetracarbonylcobalt- groups directly bonded to silicon. The corresponding hydridotetracarbonylcobalt- and heptacarbonyldicobalt-silicon compounds appear to be intermediates in the reactions.Keywords
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