Synthesis of Paracyclo(1,8)napthalenophane and Paracyclo(5,6)acenaphthenophane
- 1 August 1982
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 55 (8) , 2434-2440
- https://doi.org/10.1246/bcsj.55.2434
Abstract
[2]Paracyclo[2]paracyclo[2](1,8)naphthalenophan-9-ene-1,17-diyne, [0]paracyclo[2]paracyclo[0](5,6)acenaphthenophan-7-ene, and [2]paracyclo[2]paracyclo[2](5,6)acenaphthenophan-9-ene-1,17-diyne, were synthesized by intramolecular reductive coupling reaction of the corresponding carbonyl compounds with low-valent titanium reagent. The structures of the compounds were elucidated by NMR analyses, and the transannular π-electronic interactions between two benzene rings were examined on the basis of electronic spectra.This publication has 19 references indexed in Scilit:
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