Substitution of a platinum (II) complex without retention of stereochemistry; direct evidence for pseudorotation of a five-co-ordinate platinum (II) cationic complex containing chelating phosphine ligands
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 381-382
- https://doi.org/10.1039/c39810000381
Abstract
Ring closure of trans-[Pt(PNH2)(PNH2)Cl]+(2)[PNH2=(O-aminophenyl)diphenylphosphine; PNH2 denotes monodentate co-ordination through the phosphorus] proceeds without retention of stereochemistry; this is the first direct evidence for pseudorotation of five-co-ordinate platinum (II) complex.Keywords
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