Aromatic hydroxylation mediated by flavin autoxidation: lack of the NIH shift

1 January 1975

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 21,p. 881-882
https://doi.org/10.1039/c39750000881

Abstract

Aromatic hydroxylations by two flavin mono-oxygenase model systems show low values of the NIH shift suggesting that these oxidations are free-radical processes.

Keywords

HYDROXYLATIONS
FLAVIN AUTOXIDATION
SHOW LOW
LOW VALUES
OXYGENASE MODEL
MONO OXYGENASE
SHIFT AROMATIC
SHIFT SUGGESTING
FREE RADICAL

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