Reactions of hydrogen atoms and aliphatic radicals with monovalent cadmium and nickel ions as a source of hydrogen yield in some radiation chemical systems
- 1 January 1977
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
- Vol. 73, 622-631
- https://doi.org/10.1039/f19777300622
Abstract
The effect of CdSO4 and NiSO4 on the radiolytic hydrogen yield and its isotopic composition in the systems H2O + CH3OH, H2O + CD3OH, D2O + CH3OD, H2O +(CH3)2CHOH, H2O +(CH3)2 CDOH and D2O +(CH3)2CHOD are reported. The results suggest that hydrogen atoms and aliphatic radicals oxidize Cd+ aq and Ni+ aq. Furthermore it is suggested that the reaction Cd—C(CH3)2 OH+→ CdH++(CH3)[graphic omitted] occurs in aqueous solutions. The implications of these observations on earlier results are discussed.Keywords
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