The spin-forbidden dissociation–recombination reaction SO3?SO2+O
- 1 March 1979
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 70 (5) , 2409-2413
- https://doi.org/10.1063/1.437751
Abstract
Rate constants for the spin‐forbidden dissociation process SO3+Ar→SO2+O+Ar have been measured in shock waves between 1700 and 2500 K. The results are compared with data on the low temperature (200–400 K) recombination reaction. The analysis in terms of unimolecular reaction rate theory allows for a determination of the threshold energy of the reaction.Keywords
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