Synthese und biologische Aktivitäten von (+)‐ und (‐)‐Multifiden
- 24 December 1981
- journal article
- Published by Wiley in European Journal of Organic Chemistry
- Vol. 1981 (12) , 2266-2271
- https://doi.org/10.1002/jlac.198119811214
Abstract
(+)‐Multifiden 1, der spezifische Signalstoff für Androgameten der Braunalge Cutleria multifida, ist etwa 100fach wirksamer als das (‐)‐Enantiomere von 1. Die optische Reindarstellung beider Antipoden gelingt durch chromatographische Trennung der diastereomeren Carbamate 5a/b und 5c/d, aus denen (+)‐und (‐)‐1 in nur wenigen Schritten zugänglich sind.Keywords
This publication has 12 references indexed in Scilit:
- Stereocontrolled preparation of precursors to all primary prostaglandins from butadieneTetrahedron, 1981
- Stereoselective syntheses of "multifidenes" and related structures. Contribution to the synthetic chemistry of cis-disubstituted alken-1-ylcyclopentenesThe Journal of Organic Chemistry, 1979
- Olefinic hydrocarbons in sea-water: signal molecules for sexual reproduction in brown algaePublished by Walter de Gruyter GmbH ,1979
- Synthese von Multifiden, dem Gameten‐Lockstoff der Braunalge Cutleria multifida, und von einigen seiner Isomeren Ein Beitrag zur Cope‐Umlagerung von 1‐AlkenylcyclopentenenEuropean Journal of Inorganic Chemistry, 1978
- General method for the synthesis of high enantiomeric purity chiral epoxidesThe Journal of Organic Chemistry, 1978
- Broad spectrum methods for the resolution of optical isomers. A discussion of the reasons underlying the chromatographic separability of some diastereomeric carbamatesThe Journal of Organic Chemistry, 1977
- Automated liquid chromatography. Synthesis of a broad-spectrum resolving agent and resolution of 1-(1-naphthyl)-2,2,2-trifluoroethanolThe Journal of Organic Chemistry, 1974
- Multifidene and aucantene, C11 hydrocarbons in the male-attracting essential oil from the gynogametes of Cutleria multifida (Phaeophyta)Journal of the American Chemical Society, 1974
- Gametenlockstoffe bei niederen Pflanzen und TierenPublished by Springer Nature ,1973
- Studies on the relationship between chemical constitution and physiological actionBiochemical Journal, 1933