Trimethylsilylbis(Fluorosulfonyl)imide : An Efficient Catalyst for the Addition of Trimethylsilyl Cyanide to Carbonyl Compounds
- 1 May 1996
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 26 (10) , 1925-1929
- https://doi.org/10.1080/00397919608003546
Abstract
In the presence of 1 mol% of trimethylsilyl bis(fluorosulfonyl)imide, trimethylsilyl cyanide adds efficiently to carbonyl compounds. The catalyst has been found to be more active than trimethylsilyl triflate for the above reaction.Keywords
This publication has 6 references indexed in Scilit:
- Trimethylsilyl bis(fluorosulfonyl)imide: A new catalyst for the reactions of acetals with silyl nucleophilesTetrahedron Letters, 1993
- Trimethylsilyl trifltate catalyzed aldol-type reaction of enol silyl ethers and acetals or related compoundsTetrahedron, 1988
- N-Fluoroperfluoroalkylsulfonimides. Remarkable new fluorination reagentsJournal of the American Chemical Society, 1987
- Silicon Reagents for Organic SynthesisPublished by Springer Nature ,1983
- Trialkylsilyl Perfluoroalkanesulfonates: Highly Reactive Silylating Agents and Lewis Acids in Organic SynthesisSynthesis, 1982
- Trimethysilyl triflate in organic synthesis11Part 11 of this series. Part 10: S. Murata and R. Noyori, Tetrahedron Letters 2107 (1981).Tetrahedron, 1981