Charge-transfer properties of hydrogen bonds. III. Charge-transfer theory and the relation between the energy and the enhancement of dipole moment of hydrogen-bonded complexes
- 1 February 1973
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 58 (3) , 911-919
- https://doi.org/10.1063/1.1679344
Abstract
An extension of Mulliken's charge‐transfer theory leads to a relation between the enthalpy of formation and the enhancement of the dipole moment for hydrogen‐bonded complexes. Extensive experimental data are in accord with this theoretical prediction. It is shown conclusively that the proton transfer effect is not responsible for the enhancement of the dipole moment in these systems.Keywords
This publication has 61 references indexed in Scilit:
- Hydrogen bonds involving sulfur. I. Hydrogen sulfide dimerJournal of the American Chemical Society, 1971
- Bonding in donor-acceptor complexes. II. Electrostatic contributions to changes in the infrared spectrum of benzene-halogen complexesJournal of the American Chemical Society, 1968
- Infrared Spectra of Charge-Transfer Complexes. VI. TheoryThe Journal of Chemical Physics, 1966
- Le Rôle des Complexes A Liaisons Hydrogène “Homéotopiques” Dans Les échanges Rapides Entre ProtonsBulletin des Sociétés Chimiques Belges, 1961
- Acceptor Infrared Band Intensities in Benzene-Halogen Charge-transfer Complexes1Journal of the American Chemical Society, 1960
- Stretching Frequencies as a Function of Distances in Hydrogen BondsJournal of the American Chemical Society, 1955
- Acid-Base Reactions in Non-dissociating Solvents. Acetic Acid and Triethylamine in Carbon Tetrachloride and ChloroformJournal of the American Chemical Society, 1954
- Molecular Compounds and their Spectra. IIJournal of the American Chemical Society, 1952
- A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic HydrocarbonsJournal of the American Chemical Society, 1949
- Solubility of Iodine in 1,2- and 1,1-Dichloroethanes, cis- and trans-Dichloroethylenes and Perfluoro-n-heptaneJournal of the American Chemical Society, 1948