NMR Studies of Cyclodextrin Inclusion Complex
- 1 March 1989
- journal article
- review article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 8 (1) , 29-46
- https://doi.org/10.1080/07328308908047990
Abstract
Cyclodextrins1,2 (CDs) are cyclic oligosaccharides composed of six or more (1→4) linked α-D-glucopyranosyl residues (see FIG. 1). The common CDs are called α-, β-, and γ-CD and are constructed of six, seven, and eight α-D-glucopyranosyl units, respectively. The CD molecule is a toroidal, hollow, truncated cone with primary and secondary hydroxyl groups crowning the narrower and the wider rims, respectively. Methine protons and glucosidic oxygens are oriented in its interior and the space inside the hollow, called the cavity, is relatively hydrophobic. The internal diameter of the cavity is about 5∼9 Å for the common CDs.Keywords
This publication has 38 references indexed in Scilit:
- 1H-Nuclear Magnetic Resonance Study of 6-O-α-d-Glucopyranosyl α-Cyclodextrin - para-Nitrophenol Inclusion ComplexChemistry Letters, 1988
- 1H and 13C NMR Studies of Formation and Molecular Dynamics of Methylated-Cyclodextrin Inclusion Complexes with PhenylalanineBulletin of the Chemical Society of Japan, 1987
- Geometry of cyclohexaamylose inclusion complexes with some substituted benzenes in aqueous solution based on carbon-13 NMR chemical shiftsJournal of the American Chemical Society, 1985
- Conformation of permethylated cyclodextrins and the host-guest geometry of their inclusion complexesJournal of inclusion phenomena and molecular recognition in chemistry, 1984
- Carbon-13 NMR Study on the Cyclodextrin Inclusion Complexes in SolutionBulletin of the Chemical Society of Japan, 1981
- TIME-AVERAGED CONFORMATIONS OF THE INCLUSION COMPLEXES OF β-CYCLODEXTRIN WITH t-BUTYLPHENOLSChemistry Letters, 1980
- RELATIONSHIP BETWEEN THE CYCLODEXTRIN CATALYSES IN THE CLEAVAGES OF PHENYL ACETATES AND THE TIME-AVERAGED CONFORMATIONS OF THE INCLUSION COMPLEXESChemistry Letters, 1980
- Molecular Dynamics of the Inclusion Complexes of Cyclohexaamylose with Some Aromatic Amino Acids and DipeptidesBulletin of the Chemical Society of Japan, 1979
- Synthesis of (.+-.)-dendrotrifidiol and its naturally occurring analogs.Agricultural and Biological Chemistry, 1977
- A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic HydrocarbonsJournal of the American Chemical Society, 1949