On the relationship between crystallographic disorder and solid state dynamic behaviour in [Fe3(CO)12] and [Co4(CO)12]
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 889-891
- https://doi.org/10.1039/c39880000889
Abstract
The fluxional behaviour shown by [Fe3(CO)12] and [Co4(CO)12] in the solid state can be explained in terms of small librations involving both the encapsulated metal polyhedron and the carbonyl envelope.Keywords
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