Classical, quantum mechanical, and semiclassical representations of resonant dynamics: A unified treatment
- 1 July 1987
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 87 (1) , 284-302
- https://doi.org/10.1063/1.453625
Abstract
This paper addresses the general problem of zeroth order representation of resonant dynamics. We investigate the classical, quantum mechanical, and semiclassical transformation properties of two‐dimensional isotropic and anisotropic uncoupled harmonic oscillators. The classical and quantal theories are presented in a manner that emphasizes the strong correspondence between the two, and in particular, the SU(2) symmetry exhibited by both the classical and quantum oscillators. The classical canonical transformations relating the action‐angle variables appropriate for normal, local, and precessional motion of the isotropic oscillator are derived by explicit calculation of the generating functions. By employing a simple mapping relating the anisotropic and isotropic oscillators, expressions for action‐angle variables appropriate for the topology of an arbitrary m:n resonance are determined. The resulting invariant tori are compared with the corresponding quantum mechanical wave functions and phase space densities. The relationship between the classical and quantum mechanical theories is illustrated by determining semiclassical approximations to the unitary transformation matrix elements, which are given in terms of the classical generating functions. Applications to problems of current interest, such as the adiabatic switching method for semiclassical quantization of nonseparable systems, are briefly discussed.Keywords
This publication has 87 references indexed in Scilit:
- Lie algebraic approach to quantization of nonseparable systems with internal nonlinear resonanceThe Journal of Chemical Physics, 1986
- Unimolecular reactions and phase space bottlenecksThe Journal of Chemical Physics, 1986
- Quantum-mechanical wavepacket dynamics of the CH group in symmetric top X3CH compounds using effective Hamiltonians from high-resolution spectroscopyJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1986
- Rotational energy surfaces and high-J eigenvalue structure of polyatomic moleculesThe Journal of Chemical Physics, 1984
- Quantum manifestations of classical resonance zonesThe Journal of Chemical Physics, 1984
- The algebraic quantisation of the Birkhoff-Gustavson normal formJournal of Physics A: General Physics, 1984
- A semiclassical determination of the energy levels of a rigid asymmetric rotorThe Journal of Chemical Physics, 1978
- Search for a Universal Symmetry Group in Two DimensionsJournal of Mathematical Physics, 1970
- Symmetry and Degeneracy in Classical MechanicsPhysical Review B, 1967
- ber den Ramaneffekt des KohlendioxydsThe European Physical Journal A, 1931