Electron-transfer reactions in nitrogen fixation. Part 1. The electrosynthesis of dinitrogen, hydride, isocyanide, and carbonyl complexes of molybdenum: intermediates, mechanisms, and energetics
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 6,p. 1255-1264
- https://doi.org/10.1039/dt9850001255
Abstract
Dinitrogen, hydride, carbonyl, and isocyanide complexes of Mo0 and W0 can be electrosynthesised from the molecular substrates N2, H2, etc. and precursors trans-[MX2(Ph2PCH2CH2PPh2)2](M = MO; X = Cl, Br, I, SPh, or SBun; M = W; X = Cl), [MoH2Cl2(Ph2PCH2CH2PPh2)2], or from MoCl5 and Ph2PCH2CH2PPh2. Intermediates, mechanisms, and energetics associated with the electrosyntheses are described.Keywords
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