Mechanism of the Oxadi-π-methane and [1,3]-Acyl Sigmatropic Rearrangements of β,γ-Enones: A Theoretical Study
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (1) , 176-184
- https://doi.org/10.1021/ja9522802
Abstract
No abstract availableKeywords
This publication has 54 references indexed in Scilit:
- An MC-SCF Study of the (Photochemical) Paterno-Buchi ReactionJournal of the American Chemical Society, 1994
- Can a photochemical reaction be concerted? A theoretical study of the photochemical sigmatropic rearrangement of but-1-eneJournal of the American Chemical Society, 1992
- Gas-phase photochemistry of a .beta.,.gamma.-unsaturated ketone. Concerted and radical mechanisms of the 1,3-acetyl shift in 1,2-dimethylcyclopent-2-enyl methyl ketoneJournal of the American Chemical Society, 1986
- Photochemistry of ketones in solution. 66. Experimental evidence for the intermediacy of singlet (S1) and triplet (T2) n,.pi.* states in the [1,3]-sigmatropic acyl shift of photoexcited 3-methyl-3-(1-cyclopentenyl)butan-2-oneJournal of the American Chemical Society, 1982
- Stereospecificity in triplet state photorearrangements. Oxa-di-.pi.-methane photorearrangement. Mechanistic studies in photochemistryJournal of the American Chemical Society, 1974
- Effect of .alpha.-methyl groups on the photochemistry of 3,4,5,6,7,8-hexahydronaphthalen-2(1H)-oneJournal of the American Chemical Society, 1974
- Di-.pi.-methane and oxa-di-.pi.-methane rearrangementsChemical Reviews, 1973
- Molecular Orbital Correlation Diagrams, Mobius Systems, and Factors Controlling Ground- and Excited-State Reactions. IIJournal of the American Chemical Society, 1966
- Intersection of potential energy surfaces in polyatomic moleculesDiscussions of the Faraday Society, 1963
- Photochemical Reactions. IX.1 Isomerization of EucarvoneJournal of the American Chemical Society, 1960