Reactions of excited atomic iodine (5²P_½). Part 1.—Reaction with propane of I(5²P_½), produced by irradiation in continuum of the B³Π_0u+–X¹Σ+g system, and by collisional release in the banded region

1 January 1967

journal article
Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society

Vol. 63, 1358-1368
https://doi.org/10.1039/tf9676301358

Abstract

From the kinetics of formation of isopropyl iodide produced by irradiation of C₃H₈+I₂ mixtures with visible light, it was concluded that reaction is due to H atom abstraction by I(5²P_½). Excited atoms were produced at wavelengths above the 4995 Å threshold, due to collisional release, viz. I^* ₂+M →I M+I^*. Similar efficiencies for release were found in CO₂, N₂, Ar, C₃H₈ and H₂.

Keywords

ATOMIC
SUP
EXCITED ATOMS
VISIBLE
THRESHOLD
WAVELENGTHS
VIZ

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Reactions of excited atomic iodine (52P½). Part 1.—Reaction with propane of I(52P½), produced by irradiation in continuum of the B3Π0u+–X1Σ+g system, and by collisional release in the banded region

Abstract

Keywords

Reactions of excited atomic iodine (5²P_½). Part 1.—Reaction with propane of I(5²P_½), produced by irradiation in continuum of the B³Π_0u+–X¹Σ+g system, and by collisional release in the banded region