Photochemical expulsion of a Ru(phen)2 unit from a macrocyclic receptor and its thermal reco-ordination

1 January 2001

journal article
Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry

Vol. 25 (1) , 22-24
https://doi.org/10.1039/b007192g

Abstract

A ruthenium complex containing two 1,10-phenanthroline ligands as well as a bipyridine fragment incorporated in a macrocycle (36 atoms) has been synthesized; photoexpulsion of the Ru(phen)₂ unit from the macrocycle and its thermal reco-ordination take place efficiently and quantitatively.

Keywords

MACROCYCLE
COMPLEX CONTAINING
PHENANTHROLINE LIGANDS
TAKE PLACE
BIPYRIDINE FRAGMENT
PHOTOCHEMICAL EXPULSION
MACROCYCLIC RECEPTOR
CONTAINING TWO

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