Zum Mechanismus der Hydrolyse des Adenosin-3′.5′-cyclophosphatbenzylesters / On the Mechanism of Adenosine-3′,5′-cyclophosphatebenzylester Hydrolysis
Open Access
- 1 July 1977
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (7) , 807-809
- https://doi.org/10.1515/znb-1977-0718
Abstract
The hydrolysis of benzyltriesters of adenosine 3′,5′-cyclophosphate with H2 18O was undertaken. The mass spectra of the benzylalcohol fragments contained the label whereas the cAMP after derivatisation with trimethylsilyl-groups did not show an enhanced M + 2 peak. This clearly indicates that the benzylic C–O bond is broken during hydrolysis.Keywords
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