Thermal decomposition and carbonylation of bis(cyclopentadienyl)titanium(IV) and bis(cyclopentadienyl)zirconium(IV) derivatives

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Abstract
The reactivity and thermal lability of bis(cyclopentadienyl)dibenzyl-titanium(IV) and -zirconium(IV) have been studied; the titanium(IV) compound undergoes reductive cleavage in the presence of carbon monoxide with formation of bis(cyclopentadienyl)dicarbonyltitanium(II).