Reactions of relevance to the chemistry of aminoglycoside antibiotics. Part 9. New reagents for amination of the ethylenic linkage
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 12,p. 1682-1692
- https://doi.org/10.1039/p19780001682
Abstract
Treatment of disulphides, especially diphenyl disulphide, with chloramine-T affords a series of reagents which react with olefins to give adducts. These reactions are electrophilic in nature, with PhS+ initiating the reaction and a complex nitrogen anion terminating the process. Similar, but less extensive, experimentation has been carried out with diselenides, especially diphenyl diselenide. These new reagents provide a novel procedure for the amination of the ethylenic linkage.This publication has 0 references indexed in Scilit: