Magneto-Structural Correlations in Dimeric Copper(II) Carboxylates
- 1 September 1993
- journal article
- research article
- Published by Taylor & Francis in Molecular Crystals and Liquid Crystals
- Vol. 233 (1) , 335-344
- https://doi.org/10.1080/10587259308054975
Abstract
For dimeric copper(II) carboxylates, the most important factor determining the strength of the spin superexchange interactions is the electronic structure of the carboxylato bridge. It also has been revealed that the trigonal bipyramidal deformation of the coordination geometry around the copper atoms, and the bending of the carboxylato bridge decrease the antiferromag-netic interactions.Keywords
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