Copolymerization of CO2 and cyclohexene oxide

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Abstract
Generation of high value polymers from carbon dioxide is of general technological interest given that CO2 is both inexpensive and relatively easy to handle on an industrial scale. Previous work on the use of CO2 as a comonomer has focused primarily on development of new catalysts, and the effects of conventional process variables such as temperature and concentration on the polymerization outcome have not been examined in great detail. Recently, we, as well as Darensbourg and colleagues, have shown that one can generate zinc‐based catalysts for the polymerization of CO2 and cyclohexene oxide which produce over 400 grams of polymer per gram of metal. In this paper, we use a product of the reaction between zinc oxide and the fluorinated half‐ester of maleic anhydride to generate copolymers of CO2 and cyclohexene oxide where CO2 is both reactant and sole solvent. In general, we found that the outcome of the polymerization depends greatly on the proximity to the ceiling temperature and the critical cyclohexene oxide concentration, and also on the phase behavior of the cyclohexene oxide‐CO2 binary.
Funding Information
  • National Science Foundation
  • the U.S. Department of Energy
  • Exxon Corporation

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