Intramolecular Charge Transfer Complexes. 4. Poly(N-(2-hydroxyethyl)carbazolyl Acrylate-co-Picryl Methacrylate)
- 1 February 1981
- journal article
- research article
- Published by Taylor & Francis in Journal of Macromolecular Science: Part A - Chemistry
- Vol. 15 (3) , 405-415
- https://doi.org/10.1080/00222338108074380
Abstract
Radical copolymerization of N-(2-hydroxyethyl)carbazolyl acry-late with picryl methacrylate takes place mainly through the inter-monomeric charge transfer complex (CTC) in dioxane solution. When the solvent is 1, 2-dichloroethane, concurrent chain transfer reactions arise. The copolymers obtained are intramolecular CTC. The charge transfer interaction depends on copolymer composition and conformation, and on the copolymerization solvent.Keywords
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