Statistical Thermodynamics of Solutions of Optically Active Substances. I. Excess Free Energy of Binary Solution of d- and l-Isomers
- 1 November 1961
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 34 (11) , 1689-1693
- https://doi.org/10.1246/bcsj.34.1689
Abstract
A statistical mechanical theory of solutions consisting of d- and l-optical isomers is developed based on a new model of optically active molecules, and the excess free energy of the system is also derived and the order of magnitude of this quantity is examined.Keywords
This publication has 1 reference indexed in Scilit:
- Order and Disorder in Binary Solid SolutionsThe Journal of Chemical Physics, 1938