Preparation of aromatic nitro-compounds through nitrosodestannylation. 1,2-dihydro-3-nitrobenzocyclobutene and trimethyl-p-nitrophenylstannane
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 870-871
- https://doi.org/10.1039/p19740000870
Abstract
Cleavage of aryltrimethylstannanes by nitrosyl chloride followed by oxidation of the resulting nitroso-compound has been shown to provide a useful route to some aromatic nitro-compounds. The method is illustrated by the preparation of 1,2-dihydro-3-nitrobenzocyclobutene (‘3-nitrobenzocyclobutene’) from 1,2-dihydro-3-trimethyl-stannylbenzocyclobutene and of trimethyl-p-nitrophenylstannane from p-bis(trimethylstannyl)benzene.Keywords
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