Spectroscopic Investigation on Critical Concentration of Aqueous Electrolyte Solution
- 1 October 1984
- journal article
- research article
- Published by Taylor & Francis in Spectroscopy Letters
- Vol. 17 (10) , 633-647
- https://doi.org/10.1080/00387018408072644
Abstract
It has been assumed that the structure of binary solution may change depending on the molar ratio of solute to solvent and refer to the presence of some critical concentration where solute-solvent interactions change. Spectroscopic investigation on aqueous solutions of propylene carbonate and alkali halides have really shown presence of critical concentrations. Furthermore, the latter critical concentration of aqueous alkali halide solutions has revealed concern with the reactivity of iodide ions which have been added to the solutions. The latter finding will be the first observation of the concern between structure and reactivity of aqueous solutions.Keywords
This publication has 3 references indexed in Scilit:
- Transient spectra due to mercury atoms in aqueous solutionNature, 1978
- Apparent molal volumes of the lithium and sodium halides. Critical-type transitions in aqueous solutionThe Journal of Physical Chemistry, 1969
- A New Method of Spectrophotometric Determination of Iodine in Natural WatersBulletin of the Chemical Society of Japan, 1955