Aflatoxins Revisited: Convergent Synthesis of the ABC-Moiety

Abstract
After appropriate model studies, two methods of current preparative interest, namely radical-initiated 5-exo-trig cyclization and palladium/formate anion mediated intramolecular hydroarylation, were confronted and optimized for the convergent synthesis of the oxygenated ABC-moiety of aflatoxin B1.

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