Conformational free energy differences in steroids. Part IV. Conformational preference of the [2H3]methyl group

Abstract
The conformational preferences of the methyl and [2H3]methyl groups, measured by equilibration of 3α-methyl-5α- cholestan-6-one with its 5β-isomer, and by equilibration of the analogous 3α-[2H3]methyl compounds, were the same.

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