Syntheses and characterization of stable pseudo-octahedral tris-phenolato complexes of vanadium-(III), -(IV), and -(V)
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1004-1006
- https://doi.org/10.1039/c39900001004
Abstract
Reaction of the anionic form of the hexadentate ligand 1,4,7-tris(5-t-butyl-2-hydroxybenzyl)-1,4,7-triazacyclononane (H3L) with VCl3 in MeCN affords LVIII which is oxidized chemically and electrochemically to [LVIV]+ and [LVV]2+; electrochemical, magnetic, and electronic spectroscopic properties of these complexes and the X-ray structure of [LV][BPh4] are reported.Keywords
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