Heteronuclear Spin-Spin Coupling Constants Between Directly Bonded Atoms as a Probe of Configuration at Phosphorus Atom Involved in Diastereoisomeric 4-Methyl-1,3,2-dioxaphosphorinans
Open Access
- 1 February 1974
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 29 (1-2) , 109-112
- https://doi.org/10.1515/znb-1974-1-233
Abstract
The 1JPH and 1Jpse absolute values showed a clear dependence on the orientation of the substituents at 2-P in several pairs of substituted diastereoisomeric 2-X-2-Y-1,3,2-dioxaphosphorinans (X = H, Se, SeR; Y=O, S, OR) and may therefore provide information about conformation and configuration at phosphorus atom.Keywords
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