The synthesis and absolute configuration of thiosphingomyelins
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 329-331
- https://doi.org/10.1039/c39860000329
Abstract
Four diastereoisomers of a thiophosphoryl analogue of sphingomyelin were synthesized by a general method employing phosphoroamidites and the absolute configurations of (+)-erythro-thiosphingomyelins at phosphorus were determined by stereospecific hydrolysis in the presence of phospholipases C.Keywords
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