Kinetic Studies on Solvolysis. VII. On the Kinetic Resolution at the First Stage of the SNl-type Solvolysis of α-Phenethyl Chloride in Optically Active Carboxylic Acid Solvents
- 1 August 1961
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 34 (8) , 1137-1143
- https://doi.org/10.1246/bcsj.34.1137
Abstract
1) In SN2 displacement reactions of (±)-α-phenethyl chloride with triethylammonium (+)-α-methyl camphorate and with triethylammonium (−)-pinonate in dioxane, α-phenethyl chloride of 0.08% of optical purity (L-configuration) and of 0.15% of optical purity (L-configuration) were recovered at the stage of about 5% conversion, respectively.Keywords
This publication has 2 references indexed in Scilit:
- (+)α-Phenethyl Chloride and (-)2-Phenylpentane1Journal of the American Chemical Society, 1954
- XC.—Contributions from the Chemical Laboratory of the University of Edinburgh. No. IX. The methyl salts of camphoric acidJournal of the Chemical Society, Transactions, 1892