Isopenicillin N synthase: a new mode of reactivity
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 736-738
- https://doi.org/10.1039/c39910000736
Abstract
Incubation of δ-(L-α-aminoadipoyl)-L-(3,3-difluorohomocysteinyl)-D-valine with isopenicillin N synthase gave a thiocarboxylic acid, consistent with the formation of a monocyclic lactam intermediate.Keywords
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