O-silylated ketene acetal chemistry; β-(alkoxycarbonyl)methyl O-silyl enolates, useful synthons for α-substituted-β-(alkoxycarbonyl)methylalkanones
- 1 January 1980
- journal article
- Published by Elsevier in Tetrahedron Letters
- Vol. 21 (39) , 3779-3782
- https://doi.org/10.1016/0040-4039(80)80176-6
Abstract
No abstract availableKeywords
This publication has 11 references indexed in Scilit:
- A Convenient Synthesis of α-Phenylseleno Ketones and Aldehydes from Enol Silyl Ethers and Phenylselenenyl BromideSynthesis, 1977
- THE MICHAEL TYPE REACTION OF O-SILYLATED KETENE ACETALS WITH α,β-UNSATURATED CARBONYL COMPOUNDS PROMOTED BY TITANIUM TETRACHLORIDEChemistry Letters, 1976
- A NEW METHOD FOR THE PREPARATION OF β-HYDROXYESTERS. THE TITANIUM TETRACHLORIDE-PROMOTED REACTION OF KETENE ALKYL TRIALKYLSILYL ACETALS WITH CARBONYL COMPOUNDSChemistry Letters, 1975
- Synthesis of prostaglandins by conjugate addition and alkylation of a directed enolate ion. 11-Deoxy prostaglandinsThe Journal of Organic Chemistry, 1974
- Synthetic methods. IV. Halogenation of carbonyl compounds via silyl enol ethersThe Journal of Organic Chemistry, 1974
- O-Silylation and Attempted O-Alkylation of Lithium Ester Enolates. The Synthesis of O-Silyl Ketene AcetalsSynthetic Communications, 1973
- Ketene alkyltrialkylsilyl acetals: synthesis, pyrolysis and NMR studiesJournal of Organometallic Chemistry, 1972
- Metalated carboxylic acids v. thermal condensation of silylated ketene acetals with aromatic aldehydesTetrahedron Letters, 1972
- Silyl alkenyl ethers as the synthetic equivalent of enols. New syntheses of β-keto-sulphides and 1,3-diketonesJournal of the Chemical Society, Chemical Communications, 1972
- Chemistry of carbanions. XVIII. Preparation of trimethylsilyl enol ethersThe Journal of Organic Chemistry, 1969