Tertiary phosphine complexes of trivalent uranium: preparation and structure of U(BH4)3(dmpe)2(dmpe = Me2PCH2CH2PMe2)
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 532-533
- https://doi.org/10.1039/c39840000532
Abstract
U(BH4)3(THF)x(THF = tetrahydrofuran) reacts cleanly with excess of dmpe (dmpe = Me2PCH2CH2PMe2) producing U(BH4)3(dmpe)2; an X-ray structural analysis of this molecule has been carried out revealing U-P(1)= 3.1139(8) and U-P(2)= 3.051(9)Å.Keywords
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