Abstract
Snow and ice played important roles in determining the occurrence and timing of pH depressions in the shallow (∼1 m) nearshore waters of a small lake of the Canadian Shield. The influences of the terrestrial snowpack and lake-surface snow on the chemical composition of under-ice water were distinctly different. On land, acidic meltwater from snow was enriched with lithological elements in the soil/litter layer during lateral movement to the lake shoreline. The resulting run-off water was of relatively high ionic strength (X conductivity 55 μS cm−1), low pH (X 4.1) and contained high concentrations of Al (X 1786 μg 1−1), an element potentially toxic to aquatic biota. Snow cover on the ice surface controlled thermal conditions in the underlying water, dictating the depth to which run-off water penetrated. Uniformly cold conditions (<2°C) allowed penetration of run-off water to the substrate while under-ice warming to 4°C resulted in surface layering of less dense run-off water. flooding of the ice with lake water and melting of the ice and snow-surface cover served to counteract the effects of the run-off water through dilution.