Darstellung und Kristallstruktur von 2,4,6-Triferrocenyl- 1,3,5,2,4,6-triselenatriborinan/Synthesis and Crystal Structure of 2,4,6-Triferrocenyl-1,3,5,2,4,6-triselenatriborinane
Open Access
- 1 January 1992
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 47 (1) , 1-4
- https://doi.org/10.1515/znb-1992-0103
Abstract
The reaction of [(NEt3)FcBBr2] (Fc:C5H5FeC5H4) with bis(trim ethylsilyl)selenane leads to the formation of Fc3B3Se3 (1). 1 crystallizes in the triclinic space group P1̄. The lattice constants (at 210 K) are: a = 1487.8(8) pm , b = 1563.1(8) pm, c = 1588.6(9) pm, ɑ = 107.81(4)°, β = 101.06(4)°, γ = 115.85(4) . 1 contains a nearly planar B3Se3 ring with alternating B and Se atoms. The electronic structure of the model compound Ph3B3Se3 was investigated by ab initio SCF studies.Keywords
This publication has 0 references indexed in Scilit: