Arabinose-derived auxiliaries in asymmetric Diels–Alder reaction
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 423-424
- https://doi.org/10.1039/c39870000423
Abstract
The readily available auxiliary alcohol, benzyl 2,3-O-isopropylidene-β-L-arabinopyranoside (1), is shown to be superior to its methyl-congener (2) in asymmetric induction capacity, attributable to a more efficient shielding by the phenyl ring.Keywords
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