Characterization of Monohalogen and Monopseudohalogen Derivatives of Dimethylgermane
- 15 July 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (14) , 2622-2633
- https://doi.org/10.1139/v74-383
Abstract
The high yield syntheses of Me2GeHX (X = F, Cl, Br, I) and Me2GeHPs (Ps = CN, N3, NCO, NCS, OAc) are reported. The dimethylgermane derivatives are identified and characterized by various physical methods and by cleavage reactions where appropriate. A normal coordinate analysis based on a modified valence force field provides confirmation of the assignments for all the fundamental frequencies, except the torsional modes, in the vibrational spectra of the monohalogeno(dimethyl)germanes, Me2GeHX.Keywords
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