Concentration Dependence of NMR Spin-Lattice Relaxation Times in Solutions

Abstract
Spin‐lattice relaxation times for protons in benzene, cyclohexane, chlorobenzene, bromobenzene, and o‐dichlorobenzene in solution with carbon tetrachloride and carbon disulfide are empirically fitted to theoretical curves based on the Hill and molecular sphere models of molecular motion. The results indicate that the Hill model properly accounts for the variation of both the rotational and translational relaxation times with concentration of solute.

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