The Influence of the size and Shape of Molecules and Particles on their Electrophoretic Mobility

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Abstract
As a general rule the electrophoretic mobility of molecules and particles is solely governed by the potential at their surface of shear (ζ-potential) and does not depend on their size or shape. There are hawever two sets of exceptional conditions under which the size or shape of molecules and particles may influence their electrophoretic mobility. These are: 1) Conditions under which the ratio between the dimensions of the molecules or particles and the thickness of their diffuse ionic double layer is such that the distortion of the electric field by the particles is neither at its minimum nor at its maximum. 2) Conditions under which the molecules or particles are migrating under the influence of an electric field inside a porous medium, the size of the pores of which is such that they impede the larger molecules or particles more than the smaller ones.

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