Note on an Approximation Treatment for Many-Electron Systems
- 1 October 1934
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 46 (7) , 618-622
- https://doi.org/10.1103/physrev.46.618
Abstract
A perturbation theory is developed for treating a system of electrons in which the Hartree-Fock solution appears as the zero-order approximation. It is shown by this development that the first order correction for the energy and the charge density of the system is zero. The expression for the second-order correction for the energy greatly simplifies because of the special property of the zero-order solution. It is pointed out that the development of the higher approximation involves only calculations based on a definite one-body problem.
Keywords
This publication has 3 references indexed in Scilit:
- Note on the Interpretation of the Density Matrix in the Many-Electron ProblemMathematical Proceedings of the Cambridge Philosophical Society, 1931
- Note on Exchange Phenomena in the Thomas AtomMathematical Proceedings of the Cambridge Philosophical Society, 1930
- N herungsmethode zur L sung des quantenmechanischen Mehrk rperproblemsThe European Physical Journal A, 1930