Catalytic Methods for C-H Bond Functionalization: Application in Organic Synthesis
Top Cited Papers
- 26 September 2003
- journal article
- review article
- Published by Wiley in Advanced Synthesis & Catalysis
- Vol. 345 (9-10) , 1077-1101
- https://doi.org/10.1002/adsc.200303094
Abstract
The development of catalytic reactions involving carbon‐hydrogen bond cleavage is currently one of the most attractive research subjects in organic and organometallic chemistry. About 40 years have past since the pioneering report of the cleavage of CH bonds with transition metal complexes. Since that time, a vast number of studies of the cleavage of CH bonds, using stoichiometric amounts of transition metal complexes has appeared. In the last decade, a variety of catalytic reactions involving CH bond cleavage has been reported. In this review we briefly survey the results of these research activities with respect to the catalytic use of unreactive CH bonds in organic synthesis.Keywords
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