Dimerization and condensation of pentane-2,4-dione by MOCl4[M = Mo or W]
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 614-615
- https://doi.org/10.1039/c39740000614
Abstract
Tungsten(VI) oxide tetrachloride reacts with pentane-2,4-dione to form a salt whose single crystal X-ray structure shows a dichloro-dioxopentane-2,4-dionato-tungsten(VI) anion and a 2,4,6-trimethyl-3-acetyl-pyrylium cation; the analogus reaction with molybdenum(VI) oxide tetrachloride yields 1,3,5,7-tetramethyl-2,4,6,8-tetraoxa-adamantane.Keywords
This publication has 0 references indexed in Scilit: